Empty pork and beans into crock pot. Add Worcestershire sauce, brown sugar, ketchup and chili powder to suit your own taste. Mix ground beef, rice, salt and pepper; form into meatballs. Brown the meatballs and pour off the excess grease, then add them into crock pot on top of beans. Place sliced onion and green pepper on top of meat balls. Cook on high for 1 hour. Turn down to low and cook for an additional 4 to 6 hours.
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