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Heat oven to 350. Spray 8 or 9 in. square pan with nonstick cooking spray. In a large bowl, combine brownie mix & baking powder; mix well. Add milk, butter, vanilla and chocolate syrup from packet in brownie mix; mix well. Spread in greased pan. Bring water to boil in medium sauce pan. Add frosing-cook and stir over low heat until melted and smooth. Slowly pour over batter in pan. DO NOT STIR. Bake at 350 for 40-45 min. or until edges are bubbly and cake begins to pull away from the sides of pan. (Top may appear shiney in spots) Cool 30 mins. Serve warm or chilled.
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